活性炭电极材料的有效电阻和放电电压随时间变化规律研究
On Laws of Discharge Voltage in Time of Activated Carbon Electrode Material
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摘要: 论述了测试活性炭超级电容器材料充放电性能的方法步骤和测试结果,在此基础上,用微分方程非线性响应理论,研究材料放电电压随时间的变化规律,并得到材料的有效电阻和电容的数值以及放电电压随放电时间变化的解析式.结果表明:电容器不是线性元件,而是非线性元件;活性炭超级电容器材料放电电压随时间的变化并不遵从简单的负指数规律,而是非线性变化;用微分方程非线性响应理论得到的结果与实验测试结果符合较好.Abstract: The method and step have been discussed in this paper to test charge-discharge performance of activated carbon super capacitor materials, with the testing results received. On this basis, the change of material discharge voltage has been studied on time by nonlinear response theory of differential equations, and the effective resistance, capacitance value, and analytic expression of discharge voltage with time change been obtained. The result shows that the capacitor is nonlinear element, the discharge voltage of activated carbon super capacitor does not conform to the simple negative exponential law with time, and it is a nonlinear change; the results obtained by the nonlinear response theory of differential equations agrees well with the experimental results.
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Key words:
- activated carbon /
- supercapacitor /
- discharge voltage /
- nonlinear effect /
- effective resistance .
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[1] 蔡国营, 王亚军, 谢晶. 超级电容器储能性能[J]. 电源世界, 2009, 25(1):33-39. [2] 周亚非, 伏春平, 郑瑞倫. 基于镍-氢氧化镍超级电容器电极电容性能研究[J]. 西南大学学报(自然科学版), 2016.38(11):1-5. [3] 顾帅, 韦莉, 张逸成等. 超级电容器老化特征与寿命测试研究[J]. 中国电机工程学报, 2013, 33(21):145-153. [4] 任晓霞, 高居华, 郑瑞伦. 氢氧化镍超级电容器电极材料电流变化规律研究[J]. 人工晶体学报, 2016, 45(8):1-6. [5] WALTER G.GLÖCKLE,THEO F.Fox Function Representation of Non-Debye Relaxation Processes[J].Journal of Statistical Physics, 1993, 71(3):741-757. [6] VERMILLION R E.Nonlinearity in High-C Capacitors[J].European Journal of Physics,1998,19(2):173. [7] BULLER S, KARDEN E, KOKD, et al.Modeling the Dynamic Behavior of Supercapacitors Using Impedance Spectroscopy[J].Industry Applications Conference,2001,38(6):2500-2504. [8] WCHAYKIN W W,AMBNOREVICH A S,SYBATOV P T, et al.超级电容器充放电过程中的记忆和非线性. 传输效应[J]. 技术物理杂志, 2016, 86(2):95-104. [9] 袁斌,周蕾, 管道安.超级电容器用碳基电极材料研究进展[J]. 船电技术,2016,36(1):33-36. [10] UCHAIKIN V,SIBATOV R, UCHAIKIN D.Memory Regeneration Phenomenon in Dielectrics:The Fractional Derivative Approach[J].Physica Scripta,2009,136:014002. -
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